Crude benzene hydrogenation catalyst

The crude benzene hydrorefining catalyst has a large pore volume, a specific surface area, a clover-shaped appearance, and excellent compressive and abrasion resistance.
LSW-1 pre-hydrogenation catalyst is a W-Ni-Mo/Al2O3 catalyst with good performance for low-temperature hydrogenation of saturated dienes and alkenyl aromatic hydrocarbons, in order to extend the operation cycle of the device and prevent a large amount of highly unsaturated hydrocarbons from occurring during a hydrogenation process The polymerization reaction leads to coking on the top of the reactor. Usually, a reverse oil circulation process is used to dilute the content of diene and alkenyl aromatic hydrocarbons, while taking away a large amount of reaction heat, controlling the reaction temperature rise, and improving the selectivity of one-stage hydrogenation. At the same time, a certain amount of hydrogenation protective agent is filled on the top of the first stage bed.

Item LSW-2/2A LSW-1
Size mm Ф(1.5~2.5)×(2~8) Ф(1.5~2.5)×(2~8)
Mechanical strength,N/cm ≥150 ≥150
Pore volume, Ml/g ≥0.35 ≥0.35
Specific surface area m2/g ≥200 ≥200
Cobalt oxide content % 43895
Molybdenum trioxide content % 14-16 4~6
Tungsten oxide content % 10~12
Nickel oxide content % 4~6
Packing density kg/m3  650–750 650—750

LSW-2 is a two-stage reactor HDS catalyst. The Co-Mo /Al2O3 catalyst has remarkable low-temperature desulfurization and denitrification performance. The catalyst has high activity for C-S, C-N, and C-O bond cleavage, but has weak C-C bond cleavage. Therefore, the use of CO-MO-based catalysts has the advantages of high liquid yield, low hydrogen consumption and slow coking.
At the same time, the HBW-2 catalyst has a larger specific surface area and pore volume, and the micropore design of the carrier can hold the coke produced during the hydrogenation process.